September, 2002


To Clariant:

 

Recently I was looking for information on

Tri(laureth-4)-phosphate

[C12H25(OC2H4)3O]3PO    

a phosphoric ester based on an ethoxilated lauryl (=C12) alcohol

This is the chemical & the formula is correct;

 

the CAS Nr I gave previously was for

 phosphoric acid, dodecyl ester

CAS Nr 12751-23-4

 

NOT the same chemical

 

 

If tri(laureth-4)-phosphate has no CAS Nr would that mean it is unregulated

or not approved for use?

 

If your company is not the manufacturer, do you know who is?  *   

 

In 1989 CECA Company manufactured inipol EAP 22 & used this ingredient

plus 2-butoxyethanol * CAS Nr 111-76-2  

C6H14O2/CH3(CH2)2CH2OCH2CH2OH 10-12% of product by weight

 

plus Oleic acid - primary ingredient CH3(CH2)7CH=CH(CH2)7COOH

                                                       (Today's CAS Nr = 112-80-1 ...does it match?)

 

plus Urea NH2-CO-NH2    (Today's  CAS Nr = 57-13-6...does it match?)

 

 

Is it possible to have the help of an expert chemist and a toxicologist

to know the effect on workers? 

... when not heated? 

 

.... when heated to 100 degrees C or 194 degrees F?

(MSDS Didn't say anything about heating; later reports do)

 

How would the above listed ingredients react with each other?

The tri(laureth-4) phosphate, you say is not a stand-alone chemical... so possibly it will have reacted with 2-butoxyethanol?  There is such a chemical as Tributoxyethylphosphate (TBEP) The fact that today's inipol EAP 22 uses a simplistic instead of complex phosphate, could be an indication of problems... overkill, mind you, that may have put workers at even greater risk than first thought.

Do you have a recommendation?

 

Sincerely,

Margaret - Valdez, Alaska

 


PS  Exxon cautioned that product could be absorbed through skin; *

 not to breathe vapors...

also to

keep product out of sewers and watercourses

by diking or impounding

& keep out of extensive land areas. 

 

Inipol EAP 22 is said to be 100% soluble in water at 77 degrees F 

(Maybe so; maybe not?)

 

Doesn't sound like inipol EAP 22 should be used,

does it?

 

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